An Efficient Synthesis of Carborane Amines via One-Step Reaction of Carborane Triflates with N-Nucleophiles.

Autor: Ol’shevskaya, Valentina A., Dutikova, Yulia V., Tyutyunov, Andrei A., Kononova, Elena G., Petrovskii, Pavel V., Sung, Dae D., Kalinin, Valery N.
Předmět:
Zdroj: Synlett; 2010, Issue 8, p1265-1267, 3p
Abstrakt: 1-Trifluoromethanesulfonylmethyl-o-carborane and cesium 1-trifluoromethanesulfonylmethyl-1-carba-closo-dodecaborate react with amines in refluxing acetonitrile in the presence of NaOAc without a catalyst to give the corresponding amino derivatives. This approach allows for simple synthesis of neutral and anionic carborane amines not readily available via other synthetic routes. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index