| Autor: |
Altun, Ozlen, Dolen, Emre, Pekin, Mursit, Aboul‐Enein, HassanY. |
| Předmět: |
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| Zdroj: |
Instrumentation Science & Technology; Feb2003, Vol. 31 Issue 1, p15-21, 7p |
| Abstrakt: |
The reactions involving o-phenylenediamine (OPDA) in the presence of Cu(II) was studied and the reaction rate was found to be v = k[Cu[SUP2+]]/[o-phen]. Using a perpetual change curve, the ratio of [Cu[SUP2+]]/[o-phen] was found to be 1 : 1. The rate equations perpetual change curve demonstrates that one molecule of OPDA reacts with one Cu[SUP2+] ion and a monoimine is formed as the transfer of one electron occurs in the oxidation reaction. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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