Palladium-Catalyzed Decarboxylative Acylation of O-Phenyl Carbamates with α-Oxocarboxylic Acids at Room Temperature.

Autor: Sharma, Satyasheel, Kim, Aejin, Park, Eonjeong, Park, Jihye, Kim, Minyoung, Kwak, Jong Hwan, Lee, Sang Hwi, Jung, Young Hoon, Kim, In Su
Zdroj: Advanced Synthesis & Catalysis; Mar2013, Vol. 355 Issue 4, p667-672, 6p
Abstrakt: A palladium-catalyzed oxidative acylation of O-phenyl carbamates with α-oxocarboxylic acids via selective aromatic CH bond activation is described. This protocol represents the first ortho-acylation of phenol derivatives, and a catalytic amount of triflic acid additive is crucial for this transformation. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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