Co-NC-W and Fe-NC-W Electron-Transfer Channels for Thermal Bistability in Trimetallic {Fe6Co3[W(CN)8]6} Cyanido-Bridged Cluster.

Autor:	Podgajny, Robert, Chorazy, Szymon, Nitek, Wojciech, Rams, Michał, Majcher, Anna M., Marszałek, Bartosz, Żukrowski, Jan, Kapusta, Czesław, Sieklucka, Barbara
Zdroj:	Angewandte Chemie International Edition; Jan2013, Vol. 52 Issue 3, p896-900, 5p
Abstrakt:	Which way to choose? The trimetallic cyanide‐bridged Fe6Co3W6 cluster serves as a molecular platform for two cooperating electron‐transfer channels, WV–CN–HSCoII⇄WIV–CN–LSCoIII and WV–CN–HSFeII⇄WIV–CN–HSFeIII. {CoII3FeII6[WV(CN)8]6(MeOH)24}⋅x MeOH has a first‐order unique spin transition with thermal charge‐transfer‐induced spin transition and spin bistability that is due to a specific distribution of Co and Fe sites. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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