A study of the structure and dynamics of the hydronium ion by high resolution infrared laser spectroscopy. III. The ν3 band of D3O+.

Autor: Petek, H., Nesbitt, D. J., Owrutsky, J. C., Gudeman, C. S., Yang, X., Harris, D. O., Moore, C. B., Saykally, R. J.
Předmět:
Zdroj: Journal of Chemical Physics; 3/15/1990, Vol. 92 Issue 6, p3257, 4p
Abstrakt: 294 transitions were measured by velocity modulation spectroscopy using a difference frequency laser system with a D2/O2 discharge and assigned to the ν3 (antisymmetric stretch) band of D3O+. A simultaneous analysis of this data with the ν2 band spectra reported by Sears, et al. [J. Chem. Phys. 83, 2676 (1985)] yielded a refined set of parameters for both the ground and the excited states of both bands. The ν3 bandcenters are 2629.6512(39) and 2624.2376(47) cm-1 for the s–s and a–a inversion components, respectively. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index