Water structure in concentrated lithium chloride solutions.

Autor: Tromp, R. H., Neilson, G. W., Soper, A. K.
Předmět:
Zdroj: Journal of Chemical Physics; 6/1/1992, Vol. 96 Issue 11, p8460, 10p
Abstrakt: The radial pair distribution functions gHH(r) and gOH(r) (to a good approximation) of 1 and 10 m solutions of lithium chloride in water have been obtained from neutron diffraction. It turns out that the intermolecular water structure in a solution of 10 m is affected considerably by the presence of ions—the number of hydrogen bonds is about 70% lower than in pure water. The intermolecular water structure in 1 m lithium chloride as well as the intramolecular water structure in both 1 and 10 m lithium chloride is not distinguishable from that of pure water in any measurable extent. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index