Compression of solid nitromethane to 15 GPa at 298 K.

Autor: Yarger, F. L., Olinger, Bart
Předmět:
Zdroj: Journal of Chemical Physics; 8/1/1986, Vol. 85 Issue 3, p1534, 5p
Abstrakt: The measurement of the isothermal compression of solid nitromethane to 15 GPa at 298 K using high pressure x-ray diffraction techniques is described. The compression data are fit to a model from which bulk moduli are calculated. Most interesting are the linear compression data. The a axis direction, along which the C–N bonds are aligned, shows little increase in repulsion with increasing pressure above 5 GPa. This indicates that the nitro and methyl groups of neighboring molecules may be interacting. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index