Effects of Alkaline Ferrocyanide on Non-faradaic Yields of Anodic Contact Glow Discharge Electrolysis: Determination of the Primary Yield of OH Radicals.

Autor:	Singh, Rajeshwar, Gangal, Urvashi, Sen Gupta, Susanta
Předmět:	FERROCYANIDES ELECTROLYSIS ELECTRIC discharges ALKALINE solutions GLOW discharges IRON SINTERING
Zdroj:	Plasma Chemistry & Plasma Processing; Jun2012, Vol. 32 Issue 3, p609-617, 9p, 1 Diagram, 2 Charts, 2 Graphs
Abstrakt:	Non faradaic yields of anodic contact glow discharge electrolysis (CGDE) originate through H and OH radical generated during the process. Scavenging effects of Fe(CN) on OH radicals, in alkaline media have been investigated. A kinetic analysis of the competing reactions of O with different species in the system leads to an yield of 9.8 mol mol electron of OH and H radicals each in the liquid phase reaction zone of anodic CGDE in good agreement with the yield reported from a study involving H radical scavengers. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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