Synthesis of heterocyclic azoxy compounds from C-nitroheterocyclic compounds and metal derivatives of tert- butylamine.

Autor: Apasov, É., Shepelev, E., Dzhetigenov, B., Strelenko, Yu., Kalinin, A., Tartakovskii, V.
Zdroj: Bulletin of The Russian Academy of Sciences, Division of Chemical Science; 1992, Vol. 41 Issue 7, p1280-1281, 2p
Abstrakt: The reaction of 3-nitropyrazole and 3(5)-nitro-1,2,4-triazole with t-BuNHMgBr gives the corresponding asymmetrical diazene oxides. Furthermore, 3(5)-(1,1-dimethylethyl)azoxy-1,2,4-triazole was also synthesized by the reaction of 1-trimethylsilyl-3(5)-nitro-1,2,4-triazole with t-BuNHLi. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index