Optical study of the effect of the impurity content on the ferroelectric properties of Er3+ doped SBN glass-ceramic samples.

Autor: Haro-González, P., Martín, L. L., Pérez-Rodríguez, C., Martín, I. R., Mujica, A.
Předmět:
Zdroj: Journal of Applied Physics; Oct2011, Vol. 110 Issue 8, p084113, 4p
Abstrakt: Photoluminescence measurements have been performed on glass ceramic samples of strontium barium niobate doped with Er3+. The glass-ceramic samples were obtained from the precursor glass by thermal treatment and were doped with different contents of Er3+ ions. The average size of the nanocrystals in the samples was about 50 nm. The optical properties of the Er3+ ions were studied upon 532 nm excitation and the luminescence changes were measured as a function of temperature. The study of the luminescence spectra with increasing temperature has allowed us to ascertain the occurrence of the ferroelectric-paraelectric phase transition in the strontium barium niobate nanocrystals embedded in the glass matrix. We have particularly focused on the temperature range around the Curie temperature, when the system undergoes the transition from the ferroelectric phase to the paraelectric phase. Doping of the strontium barium niobate samples results in a change in the measured value of the Curie temperature which induces a change in the ferroelectric properties. It is interesting to note that this phase transition in the nanocrystals immersed in the glass matrix had previously not been detected. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index