| Autor: |
Hlushak, S. P., Trokhymchuk, A. D., Sokołowski, S. |
| Předmět: |
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| Zdroj: |
Journal of Chemical Physics; 3/21/2011, Vol. 134 Issue 11, p114101, 10p, 8 Graphs |
| Abstrakt: |
The direct correlation function of the complex discrete potential model fluids is obtained as a linear combination of the first-order mean spherical approximation (FMSA) solution for the simple square well model that has been reported recently [Hlushak et al., J. Chem. Phys. 130, 234511 (2009)]. The theory is employed to evaluate the structure and thermodynamics of complex fluids based on the square well-barrier and square well-barrier-well discrete potential models. Obtained results are compared with theoretical predictions of the hybrid mean spherical approximation, already reported in the literature [Guillen-Escamilla et al., J. Phys.: Condens. Matter 19, 086224 (2007)], and with computer simulation data of this study. The compressibility route to thermodynamics is then used to check whether the FMSA theory is able to predict multiple fluid-fluid transitions for the square barrier-well model fluids. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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