New aggregation-induced emission enhancement materials combined triarylamine and dicarbazolyl triphenylethylene moietiesElectronic supplementary information (ESI) available: UV-vis and PL spectra, and CV curves of 1B-TPAand 2B-TPA. See DOI: 10.1039/c0jm00599a

Autor: Haiyin Li, Zhenguo Chi, Bingjia Xu, Xiqi Zhang, Zhiyong Yang, Xiaofang Li, Siwei Liu, Yi Zhang, Jiarui Xu
Zdroj: Journal of Materials Chemistry; 8/7/2010, Vol. 20 Issue 29, p6103-6110, 8p
Abstrakt: A new class of compounds containing triarylamine and dicarbazolyl triphenylethylene moieties with high thermal stability and aggregation-induced emission enhancement properties was synthesized. The glass transition temperature and 5% weight loss temperature of 3B-TPA are up to 214.3 °C and 516.8 °C, respectively. The compounds exhibited significant photoinduced intramolecular charge-transfer properties. The aggregation considerably affected the π–π* transition and resulted in 6–7 nm red shift of the π–π* absorption wavelength at the peak in UV-vis spectra. The compounds could emit intense blue-green light in aggregated states. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index