Resolution of chiral polyoxoanion [P2Mo18O62]6−with histidineElectronic supplementary information (ESI) available: Complementary figures for the crystal structure and IR (Fig. S7), UV (Fig. S8, S9 and S10), TG spectra (Fig. S11) and polarizing optical micrograph (Fig. S12) of complex 1. CCDC reference numbers 761260for 1a, 761261for 1b. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c001160f

Autor:	Ding Liu, Hua-Qiao Tan, Wei-Lin Chen, Yang-Guang Li, En-Bo Wang
Předmět:	CHIRALITY ANIONS SOLUTION (Chemistry) TARTARIC acid SEPARATION (Technology) MOLECULAR structure ORGANIC synthesis
Zdroj:	CrystEngComm; Jul2010, Vol. 12 Issue 7, p2044-2046, 3p
Abstrakt:	The classical Dawson-type racemic polyoxoanions [P2Mo18O62]6−have been separated in aqueous solution with l,d-histidine, respectively. Two enantiomerically pure compounds: H3(L-HC6H9N3O2)3[P2Mo18O62]·20H2O (1a), H3(D-HC6H9N3O2)3[P2Mo18O62]·20H2O (1b), have been synthesized. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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