Influence of encapsulation on the mechanism of thermal decomposition of hexacyanotransition metal complexes.

Autor: Gol'tsov, Yu., Matkovskaya, L., Solomakha, V., Glukhoi, A., Grabovyi, P., Golovatyi, V., Il'in, V.
Zdroj: Theoretical & Experimental Chemistry; Mar1999, Vol. 35 Issue 2, p103-108, 6p
Abstrakt: It has been established that, in contrast to the pure substances, the thermal decomposition of hexacyanotransition metal complexes, encapsulated in the large cavities of faujasite, occurs by a hydrolytic mechanism. The composition of the gaseous products of the thermal decomposition depend on the characteristics of the localization of the cations in the inclusion compounds. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index