Toward a quantum-mechanical description of metal-assisted phosphoryl transfer in pyrophosphate.

Autor: Heikinheimo, P., Tuominen, V., Ahonen, A.-K., Teplyakov, A., Cooperman, B.S., Baykov, A.A., Lahti, R., Goldman, A.
Předmět:
Zdroj: Proceedings of the National Academy of Sciences of the United States of America; 03/13/2001, Vol. 98 Issue 6, p3121, 6p, 7 Diagrams, 1 Chart
Abstrakt: Presents a quantum-mechanical description of metal-assisted phosphoryl transfer in pyrophosphatase. Characterization of the complex active site; Up and down conformations in the active site; Diagram of superimposed A-active-site structures; Sources of catalytic power in pyrophosphatase.
Databáze: Complementary Index