Crystallization of chiral thiourea derivatives of 1-phenylethylamine: transfer of stable motifs from racemic to homochiral environment.

Autor: Frantsuzova, Lyubov V., Gerasimova, Daria P., Metlushka, Kirill E., Badeeva, Elena K., Nikitina, Kristina A., Zinnatullin, Ruzal G., Ivshin, Kamil A., Kataeva, Olga N., Lodochnikova, Olga A.
Předmět:
Zdroj: Structural Chemistry; Dec2024, Vol. 35 Issue 6, p1963-1980, 18p
Abstrakt: In a series of three chiral thioureas with a 1-phenylethylamine fragment, none of the homochiral samples forms "true chiral" hydrogen-bonded motifs in the crystal, but forms dimers or chains with local symmetry from the interacting fragments, consistent with the racemic crystal pattern. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index