| Autor: |
Tian, Ye, Sun, Hanying, Cui, Benqiang, Han, Shaoyue, Wang, Tianle, Shi, Yanhui, Cao, Changsheng |
| Předmět: |
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| Zdroj: |
Chemical Communications; 10/25/2024, Vol. 60 Issue 83, p11980-11983, 4p |
| Abstrakt: |
The cleavage of heteroaromatic endocyclic carbon–heteroatom bonds to assemble C–Si bonds is scarce. Here, we demonstrate an unprecedented dearomatization silylation of N-arylindoles arising from reductive activation initiated by electron-rich silylboronic complexes to deliver silyl styrenes with perfect stereoselectivity. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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