2,3-Bis(2-pyridyl)thieno[3,4-b]pyrazine and its ruthenium(II) complexes: a new bidentate bridging ligand for enhanced metal–metal communication.

Autor: Konkol, Kristine L., Wilcox, Wyatt D., Rasmussen, Seth C.
Předmět:
Zdroj: Dalton Transactions: An International Journal of Inorganic Chemistry; 10/28/2024, Vol. 53 Issue 40, p16685-16692, 8p
Abstrakt: A new bidentate bridging ligand, bis(2-pyridyl)thieno[3,4-b]pyrazine is reported, along with its mono- and bi-metallic Ru(II) complexes as representative examples. Spectroscopic, electrochemical and X-ray crystallographic characterization of these species is reported, with the separation of the two Ru(III)/Ru(II) couples of the bimetallic complex suggesting better metal–metal communication than classical polypyridyl analogues. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index