| Autor: |
Li, Weixiang, Zhang, Ruipu, Zhou, Naifu, Lu, Jiaqing, Fu, Niankai |
| Předmět: |
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| Zdroj: |
Chemical Communications; 10/21/2024, Vol. 60 Issue 82, p11714-11717, 4p |
| Abstrakt: |
We report a dual transition metal electrocatalytic approach for C(sp3)–C(sp3) bond cleavage and arylation of cyclic alcohols, providing an efficient and sustainable method for site-specific arylation of ketones. The reaction involves electrophotochemical cerium-catalysed generation of alkoxyl radicals from readily accessible alcohols. Subsequently, homolytic cleavage of the β-C–C bond leads to the generation of carbon-centered radicals that could be effectively utilized by nickel catalysis powered by cathode reduction to deliver the remote arylated ketone products. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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