Autor: |
Cooney, Shannon E., Schreiber, Eric, Ferrigno, Baela M., Matson, Ellen M. |
Předmět: |
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Zdroj: |
Chemical Communications; 5/28/2024, Vol. 60 Issue 43, p5610-5613, 4p |
Abstrakt: |
We report the transfer of H-atoms from a reduced polyoxovanadate alkoxide [nOct4N][V6O6(OH2)(OMe)12] via concerted proton–electron transfer. Oxygen reduction is compared between bridging and terminal O–H bonds revealing similar mechanisms, providing new insight to design criteria for metal-oxide electrocatalysts that faciliate oxygen reduction by concerted-proton electron transfer. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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