Photoconductivity in self-assembled CuO thin films.

Autor: Anand, Akhil M., Raj, Aruna, Salam, Jishad A., Adithya Nath, R., Jayakrishnan, R.
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Zdroj: Materials for Renewable & Sustainable Energy; Apr2024, Vol. 13 Issue 1, p45-58, 14p
Abstrakt: Self-assembly is the most promising low-cost and high-throughput methodology for nanofabrication. This paper reports the optimization of a self-assembly process at room temperature for the growth of copper oxide (CuO) based nanostructures over a copper substrate using aqueous potassium hydroxide (KOH) solution as the oxidizing agent. The monoclinic phase of CuO nanostructures grown over the copper substrate was confirmed from the X-ray diffraction (XRD) and micro-Raman analysis. The overall chemical composition of nanostructures was confirmed to be that of CuO from its oxidation state using X-ray photoelectron spectroscopy (XPS). Photodetectors were engineered with the structure Cu/CuO/Ag. The photodetectors exhibited a response to both ultraviolet and visible light illumination. The optimized Cu/CuO/Ag structure exhibits a responsivity of ~ 1.65 µA/W, with an ON:OFF ratio of ~ 69 under a bias voltage of 0.01 V. The temporal dependence of photo-response for the optimized photodetector displayed the persistent nature of photoconduction indicating a delay in charge carrier recombination which could potentially be exploited for photovoltaic applications. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index