| Autor: |
Oliver, Gwyndaf A., Kolb, Simon, Werz, Daniel B. |
| Předmět: |
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| Zdroj: |
Synlett; Jun2024, Vol. 35 Issue 9, p963-966, 4p |
| Abstrakt: |
This article discusses the electrocatalytic synthesis of 1,2-dioxolanes from tetrasubstituted donor-acceptor cyclopropanes. The use of electrochemical activation allows for an alternative cleavage mode of C(sp3)-C(sp3) bonds, resulting in the formation of 1,2-dioxolanes. The study explores the optimization and reaction scope of this system, demonstrating the synthesis of 3,3,5,5-tetrasubstituted dioxolanes from various cyclopropanes. The proposed mechanism for this reaction is supported by previous studies on the electrochemical activation of donor-acceptor cyclopropanes. [Extracted from the article] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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