| Autor: |
Andren, Max, Bosch, Eric, Krueger, Herman R., Groeneman, Ryan H. |
| Předmět: |
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| Zdroj: |
CrystEngComm; 3/14/2024, Vol. 26 Issue 10, p1349-1352, 4p |
| Abstrakt: |
The solid-state [2 + 2] cycloaddition reaction of trans-1,2-bis(2-pyridyl)ethylene through both co-crystallization and mechanical grinding is reported. The photoreaction is achieved by using iodoperchlorobenzene as a molecular template. The co-crystal is sustained primarily by I⋯N halogen bonds and homogeneous face-to-face π–π stacking interactions. The combination of these non-covalent forces ultimately places the reactant in a suitable position to photoreact. In addition, a pair of photoreactive solids were also achieved through a solvent-free mechanical grinding approach with similar yields. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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