Synthesis and Porous Crystal Structure of a New Tetranuclear Cluster Based on a Calix[4]Arene Functionalized at the Upper Rim by Distal p-(4-Nitrophenyl)Diazenyl and p-tert-Butyl Groups.

Autor:	Ovsyannikov, A. S., Strelnikova, Yu. V., Iova, A. A., Agarkov, A. S., Islamov, D. R., Dorovatovskii, P. V., Solovieva, S. E., Antipin, I. S.
Předmět:	CRYSTAL structure X-ray diffraction POLAR effects (Chemistry) INFORMATION display systems MANGANESE chlorides SUPRAMOLECULAR chemistry RESORCINARENES
Zdroj:	Journal of Structural Chemistry; Feb2024, Vol. 65 Issue 2, p313-322, 10p
Abstrakt:	New crystalline tetranuclear cluster is prepared by the interaction of manganese(II) chloride with calix[4]arene 3 functionalized at the upper rim by distal p-(4-nitrophenyl)diazenyl and p-tert-butyl groups displaying different electronic effects and sizes. The structure of the cluster is studied by single-crystal XRD. Due to the presence of (4-nitrophenyl)diazenyl moieties at the upper rim of the macrocyclic ligand, the molecules of the tetranuclear clusters are involved in π-stacking interactions leading to the formation of 2D supramolecular layers affording a porous crystal packing. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
Externí odkaz:	Zobrazit plný text záznamu Full text from SpringerLink