Autor: |
Parashar, Ritu, Nailwal, Bipin Chandra, Goswami, Nitesh, Lenka, Raja Kishora, Singha, Amit Kumar, Kar, Soumitra, Adak, Asis Kumar, Parida, Suresh Chandra, Mukhopadhyay, Sulekha |
Předmět: |
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Zdroj: |
Indian Chemical Engineer; Dec2023, Vol. 65 Issue 6, p556-573, 18p |
Abstrakt: |
The hydrogen in the vent gas stream of the hydrocracker (used to produce bio-jet fuel) cannot be reused since it has many impurities. The metal membrane can be a potential candidate for recovering hydrogen from this vent gas. In this work, the authors report the development of a composite palladium membrane and its application, for the first time, in the recovery of hydrogen from a simulated vent gas environment. A dense thin film (thickness ~3 µm) of Pd metal was coated on a ceramic support tube by the sputter deposition technique. The hydrogen permeance of the Pd membrane was found to be 18.75 × 10-6 mol·m-2·h-1·Pa-1, which was reduced to 3.25 × 10-6 mol·m-2·h-1·Pa-1, with an exposure of 100 h in the simulated bio-jet fuel environment. To avoid the loss of permeability, a thin layer of Pt can be coated over the Pd membrane. The present study used MATLAB software to simulate the Pt-coated Pd composite membrane performance in the bio-jet fuel production environment. Simulation studies confirmed that a membrane area of ~95 cm² (250 mm length and 12 mm OD) is sufficient for the complete recovery of hydrogen from the vent gas stream of hydrocracker at a feed velocity of 0.075 m/s. [ABSTRACT FROM AUTHOR] |
Databáze: |
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Externí odkaz: |
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