Reduction-induced hapticity increase in a silacycle-bridged biaryl-based ligand coordinated to an iron center.

Autor: Suga, Yuto, Sunada, Yusuke
Předmět:
Zdroj: Dalton Transactions: An International Journal of Inorganic Chemistry; 1/21/2024, Vol. 53 Issue 3, p862-865, 4p
Abstrakt: An Fe(II) bromide complex supported by a bidentate phosphine ligand and an η1(C)-coordinated six-membered silacycle-bridged biphenyl-based ligand is converted upon reduction into an Fe(I) complex in which the hapticity of the silacycle-based ligand increases from η1 to η5. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index