Preparation and characterization of high performance coal tar pitch-based carbon fiber.

Autor: Zhang, Dakui, Mu, Chunfeng, He, Ying, Lai, Wei, Liu, Haifeng, Liu, Qingpei, Yao, Jun, Zhang, Xinyu, Wang, Xiaonan, Xue, Zhanqiang, Nie, Yi, Song, Kedong
Předmět:
Zdroj: Fullerenes, Nanotubes & Carbon Nanostructures; 2024, Vol. 32 Issue 2, p128-140, 13p
Abstrakt: High performance carbon fiber based on coal tar pitch is a new type of functional material with unique properties, such as light weight, high strength, high modulus, high thermal conductivity, high electrical conductivity and low thermal expansion coefficient. It is a new type of functional material for both military and civilian use. In order to study the preparation of high performance carbon fiber based on coal tar pitch, this article obtained high performance carbon fiber based on coal tar pitch through raw material pretreatment, spinnable asphalt modulation, asphalt melt spinning, non-melting, carbonization, graphitization and other processes, and characterized the performance of spinnable mesocase asphalt and carbon fiber. The results show that high-performance spinnable mesophase pitch can be prepared by three steps raw material refining, hydrogenation modification and thermal polymerization. The mesophase content is 95%, the softening point is 280 °C, and the 3000 m filament can be spun under melt spinning conditions of 375 °C and 0.01 MPa. After graphitization, the coal pitch-based carbon fiber has excellent mechanical properties, small structural defects and a diameter of 12 μm. The tensile strength is 3089 MPa, the elastic modulus is 689 GPa, and the thermal conductivity is 902 w/(m·K). [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index