Catalyst- and metal-free C(sp2)–H bond selenylation of (N-hetero)-arenes using diselenides and trichloroisocyanuric acid at room temperature.

Autor: Neto, José S. S., Granja, Isis J. A., Scheide, Marcos R., Franco, Marcelo S., Moraes, Cassio A. O., Beatriz, Adilson, de Lima, Dênis P., Botteselle, Giancarlo V., Frizon, Tiago E. A., Saba, Sumbal, Rafique, Jamal, Braga, Antonio L.
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Zdroj: Scientific Reports; 11/22/2023, Vol. 13 Issue 1, p1-13, 13p
Abstrakt: In this paper, we report an eco-friendly approach for the C(sp2)–H bond selenylation of imidazopyridines and other N-heteroarenes as well as simple arenes at ambient temperature. This new protocol consists of the reaction between (N-hetero)-arenes and the diorganyl-diselenides and trichloroisocyanuric acid (TCCA)-ethanol reagent system. In a short reaction time, the desired selenylated products were obtained regioselectively in good yields, with tolerance for a wide range of functional groups. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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