Crystal structure and Hirshfeld surface analysis of poly[[tetraaqua(μ-1,3,4,7,8,10,12,13,16,17,19,22-dodecaazatetracyclo[8.8.4.13,17.18,12]tetracosane- 5,6,14,15,20,21-hexaonato)iron(IV)dilithium] tetrahydrate].

Autor:	Plutenko, Maksym O., Shova, Sergiu, Pavlenko, Vadim A., Golenya, Irina A., Fritsky, Igor O.
Předmět:	SURFACE analysis CRYSTAL structure SURFACE structure IRON ANIONS DIMERS
Zdroj:	Acta Crystallographica Section E: Crystallographic Communications; Nov2023, Vol. 79 Issue 11, p1059-1062, 12p
Abstrakt:	The title compound, [FeLi2(C12H12N12O6)(H2O)4]⋅4H2O, consists of iron complex anions, lithium cations and water molecules. The complex anion shows a clathrochelate topology. The coordination geometry of the FeIV centre is intermediate between a trigonal prism and a trigonal antiprism. In the crystal, the complex anions are connected through two Li cations into dimers, which are connected by Li--O bonds, forming infinite chains along the b-axis direction. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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