| Autor: |
Sharma, Ankur, Yadav, Pinki, Bhaumik, Indranil, Singh, M. N., Sathe, Vasant, Singh, Gurvinderjit |
| Předmět: |
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| Zdroj: |
Journal of Applied Physics; 7/28/2023, Vol. 134 Issue 4, p1-12, 12p |
| Abstrakt: |
A structural crossover from non-ergodic to ergodic phase in niobium doped (Na0.41K0.09Bi0.5)TiO3, i.e., (Na0.41K0.09Bi0.50)1−x/2(Ti1−xNbx)O3 was investigated using high resolution x-ray diffraction and Raman spectroscopy. The diffraction studies reveal the co-existence of cubic (Pm3m), rhombohedral (R3c), and tetragonal (P4bm) phases for lower concentrations of niobium, i.e., for x ≤ 0.005 and the emergence of the pseudo-cubic (Pm3m) structure for higher niobium contents (for x ≥ 0.0075). On the other hand, Raman spectroscopy reveals the augmentation of the tetragonal phase with niobium content. These observations advocate the crossover from the non-ergodic to ergodic phase with niobium content. The presence of the pseudo-cubic phase (Pm3m), especially for x ≥ 0.0075, does not indicate the existence of the long-range cubic phase; rather, it models the contribution of nano-regions with the tetragonal symmetry as indicated in the Raman measurements. It further suggests that, with the incorporation of niobium, the size polar nano-regions diminish that leads to the crossover from the non-ergodic to ergodic phase. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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