| Autor: |
Fedorenko, A. D., Asanov, I. P., Asanova, T. I., Vasil'chenko, D. B., Nikolenko, A. D., Piminov, P. A., Karyukina, K. Yu. |
| Zdroj: |
Bulletin of the Russian Academy of Sciences: Physics; May2023, Vol. 87 Issue 5, p654-661, 8p |
| Abstrakt: |
Cl K-edges of a wide range of chlorides of 4d and 5d transition metals {MCl6}n− (M = Rh, Pd, Re, Os, Ir, Pt) are obtained using the Kosmos station of the VEPP-4 synchrotron. The combined use of experimental X-ray and theoretical means allows determination of the magnitude of spin–orbit coupling (SOC), depending on the transition metal. The features of the Cl K-edge are analyzed with and without SOC, and upon stretching and compression of the complexes. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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