Synthesis of adamantane by ionic liquid-promoted isomerization of tricyclo[5.2.1.02,6]decane and H2SO4-mediated hydroisomerization of pentacyclo[4.4.0.02,4.03,7.08,10]decane.

Autor: Aminov, R. I., Ramazanov, I. R., Khusnutdinov, R. I.
Předmět:
Zdroj: Russian Chemical Bulletin; Jan2022, Vol. 71 Issue 1, p102-106, 5p
Abstrakt: Adamantane was synthesized by skeletal isomerization of endo- and exo-tricyclo[5.2.1.02,6]-decanes in the presence of ionic liquid [Et3NH]+[Al2Cl7]−—CuSO4. A new method to synthesize adamantane in 75% yield by H2SO4-mediated hydroisomerization of its new precursor, pentacyclo[4.4.0.02,4.03,7.08,10]decane, was developed. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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