Nitrous oxide as a diazo transfer reagent: the synthesis of triazolopyridines.

Autor: Landman, Iris R., Fadaei-Tirani, Farzaneh, Severin, Kay
Předmět:
Zdroj: Chemical Communications; 11/11/2021, Vol. 57 Issue 87, p11537-11540, 4p
Abstrakt: Nitrous oxide is a potential diazo transfer reagent, but its applications in organic chemistry are scarce. Here, we show that triazolopyridines and triazoloquinolines are formed in the reactions of metallated 2-alkylpyridines or 2-alkylquinolines with N2O. The reactions can be performed under mild conditions and give synthetically interesting triazoles in moderate to good yields. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index