| Autor: |
Zheng, Hui, Ding, Changhao, Xu, Han-Shu, Tang, Lulu, Liu, Huimin, Wei, Lianwei, Tang, Kaibin |
| Předmět: |
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| Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 10/7/2021, Vol. 50 Issue 37, p13052-13058, 7p |
| Abstrakt: |
Several FeS-derived intercalated compounds (C2H8N2)xFeS and Ax(C2H8N2)yFeS (A = Li, Na) were successfully synthesized via a novel ammonothermal method. The powder X-ray diffraction (XRD) measurements reveal that the FeS intercalated samples have the same tetragonal crystal structure as the parent FeS. After intercalation, these three as-synthesized samples do not show superconductor behavior, which is confirmed by the magnetization and the electrical resistivity measurements. (C2H8N2)xFeS exhibits paramagnetic semiconductor behavior, while the newly synthesized Ax(C2H8N2)yFeS (A = Li, Na) shows antiferromagnetic semiconductor behavior. The absence of superconductivity in these FeS-derived compounds should be closely related to the iron vacancies in the FeS layer. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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