| Autor: |
Sheldon, Daniel J., Crimmin, Mark R. |
| Předmět: |
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| Zdroj: |
Chemical Communications; 7/25/2021, Vol. 57 Issue 58, p7096-7099, 4p |
| Abstrakt: |
The room-temperature activation of SF6, a potent greenhouse gas, is reported using a monovalent aluminium(I) reagent to form well-defined aluminium(III) fluoride and aluminium(III) sulfide products. New reactions have been developed to utilise the aluminium(III) fluoride and aluminium(III) sulfide as a nucleophilic source of F− and S2− for a range of electrophiles. The overall reaction sequence results in the net transfer of fluorine or sulfur atoms from an environmentally detrimental gas to useful organic products. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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