Autor: |
Zeng, Linwei, Jin, Jian, He, Jixiao, Cui, Sunliang |
Předmět: |
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Zdroj: |
Chemical Communications; 7/14/2021, Vol. 57 Issue 55, p6792-6795, 4p |
Abstrakt: |
A photo-induced imidation process of carboxylic acids is described. Numerous carboxylic acids could convert to β-sulfonyl imides in the presence of N-sulfonyl ynamides under visible light irradiation. Control experiments and mechanistic studies demonstrate that this imidation process involves a hydroacyloxylation/radical rearrangement cascade. This protocol represents a direct imidation method from carboxylic acids under mild conditions, with broad scope and high atom-economy. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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