Photo-induced synthesis of β-sulfonyl imides from carboxylic acids.

Autor: Zeng, Linwei, Jin, Jian, He, Jixiao, Cui, Sunliang
Předmět:
Zdroj: Chemical Communications; 7/14/2021, Vol. 57 Issue 55, p6792-6795, 4p
Abstrakt: A photo-induced imidation process of carboxylic acids is described. Numerous carboxylic acids could convert to β-sulfonyl imides in the presence of N-sulfonyl ynamides under visible light irradiation. Control experiments and mechanistic studies demonstrate that this imidation process involves a hydroacyloxylation/radical rearrangement cascade. This protocol represents a direct imidation method from carboxylic acids under mild conditions, with broad scope and high atom-economy. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index