Investigation in the Area of Furan Acetal Compounds. 13. Synthesis and Structure of 1,3-Dioxacyclanes Based on Furfural and Glycerol.

Autor: Gromachevskaya, E. V., Kvitkovsky, F. V., Usova, E. B., Kulnevich, V. G.
Předmět:
Zdroj: Chemistry of Heterocyclic Compounds; Aug2004, Vol. 40 Issue 8, p979-985, 7p
Abstrakt: The optimum conditions were found for the condensation of glycerol with furfural. It was shown that the reaction of glycerol with furfural gives a mixture of the cis and trans isomers of five- and six-membered furan 1,3-dioxacyclanes. The cis- and trans-5-hydroxy-2-furyl-1,3-dioxanes were isolated by column chromatography, and their stereochemical structure was established by IR and NMR spectroscopy. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index