| Autor: |
Zhang, Yue, Lu, Jing, Lan, Tianlei, Cheng, Shaoling, Liu, Wei, Chen, Chao |
| Předmět: |
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| Zdroj: |
European Journal of Organic Chemistry; 1/22/2021, Vol. 2021 Issue 3, p436-442, 7p |
| Abstrakt: |
The preparation of a new class of aliphatic amino iodane(III) reagents has been realized with the N‐TMS−amine and acetoxybenziodazole participated in the formation of N−I bond. The amino‐containing iodane(III) reagent 2 d was characterized by single‐crystal X‐ray diffraction, which revealed the expected hypervalent iodane distorted T‐shaped geometry. A practical copper‐catalyzed, directed electrophilic amination of aryl amines employing amino‐iodane(III) as amination agents was disclosed that proceeded smoothly without external additives. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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