Modifying the luminescent properties of a Cu(I) diphosphine complex using ligand-centered reactions in single crystals.

Autor: Lee, Kyounghoon, Lai, Po-Ni, Parveen, Riffat, Donahue, Courtney M., Wymore, Mikayla M., Massman, Blake A., Vlaisavljevich, Bess, Teets, Thomas S., Daly, Scott R.
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Zdroj: Chemical Communications; 8/18/2020, Vol. 56 Issue 64, p9110-9113, 4p
Abstrakt: Here we report how reactions at a chemically reactive diphosphine shift the long-lived luminescent colour of a crystalline three-coordinate Cu(I) complex from green to blue. The results demonstrate how vapochromism and single-crystal-to-single-crystal transformations can be achieved using ligand-centered reactions. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index