An effective cis-β-octahedral Mn(iii) SALPN catalyst for the Mukaiyama–Isayama hydration of α,β-unsaturated esters.

Autor: Donnelly, Paul S., North, Andrea J., Radjah, Natalia Caren, Ricca, Michael, Robertson, Angus, White, Jonathan M., Rizzacasa, Mark A.
Předmět:
Zdroj: Chemical Communications; 7/7/2019, Vol. 55 Issue 53, p7699-7702, 4p
Abstrakt: Two cis-β-MnIIISALPN catalysts were synthesised and tested in the Mukaiyama–Isayama hydration of α,β-unsaturated esters. The MnIIIEtOSALPN(acac) complex 7 is the most active and catalyses hydration with little or no detectable undesired alkene reduction. This catalyst is superior for alkene hydration compared to the originally reported Mn(dpm)3 catalyst. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index