Hydrogenation of Furfural to Furfuryl Alcohol in the Presence of Ru-Containing Catalysts Based on New Zeolite-Like Materials.

Autor: Kurchenko, Yu. V., Simakova, I. L., Demidova, Yu. S., Panchenko, V. N., Timofeeva, M. N.
Zdroj: Catalysis in Industry; Apr2019, Vol. 11 Issue 2, p130-137, 8p
Abstrakt: Catalytic liquid-phase hydrogenation of furfural to commercially important furfuryl alcohol was studied in the presence of Ru-containing catalysts based on Sibunit and zeo-type materials, such as nickel phosphate molecular sieves (VSB-5 and Fe-VSB-5) and zirconium-containing metal–organic frameworks (UiO-66(Zr)-R, R = H and NH2), at 30 and 50°C and 5–25 atm of hydrogen. The yield of furfuryl alcohol was found to depend on the nature of the support and increases in the following order: Ru/UiO-66(Zr)-NH2 < Ru/UiO-66(Zr) < Ru/Fe-VSB-5 < Ru/VSB-5. The effect of hydrogen pressure and temperature on the selectivity toward furfuryl alcohol was investigated. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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