Alcohol-Directed ortho -C–H Alkenylation.

Autor: Li, Li, Liu, Qinglan, Chen, Jiean, Huang, Yong
Předmět:
Zdroj: Synlett; 2019, Vol. 30 Issue 11, p1366-1370, 5p
Abstrakt: We report a simple and mild dehydrogenative cross-coupling reaction of unprotected arylethanols and acrylates. Unlike the case of previous reactions, in which prior functionalization of the substrate with a metal-coordinating site was required, free primary, secondary, or tertiary hydroxy groups were found to be effective directing groups for the ortho -C–H palladation and subsequent olefination. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index