Carbon Dioxide-Free Hydrogen Production with Integrated Hydrogen Separation and Storage.

Autor:	Dürr, Stefan, Müller, Michael, Jorschick, Holger, Helmin, Marta, Bösmann, Andreas, Palkovits, Regina, Wasserscheid, Peter
Předmět:	HYDROGEN production CARBON dioxide CARBON compounds CHEMICAL decomposition CHEMICAL kinetics
Zdroj:	ChemSusChem; 1/10/2017, Vol. 10 Issue 1, p42-47, 6p
Abstrakt:	An integration of CO2-free hydrogen generation through methane decomposition coupled with hydrogen/methane separation and chemical hydrogen storage through liquid organic hydrogen carrier (LOHC) systems is demonstrated. A potential, very interesting application is the upgrading of stranded gas, for example, gas from a remote gas field or associated gas from off-shore oil drilling. Stranded gas can be effectively converted in a catalytic process by methane decomposition into solid carbon and a hydrogen/methane mixture that can be directly fed to a hydrogenation unit to load a LOHC with hydrogen. This allows for a straight-forward separation of hydrogen from CH4 and conversion of hydrogen to a hydrogen-rich LOHC material. Both, the hydrogen-rich LOHC material and the generated carbon on metal can easily be transported to destinations of further industrial use by established transport systems, like ships or trucks. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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