Nickel(II) di(pentyl)dithiocarbamates with P ligands.

Autor: Pastorek, Richard, Kameníček*, Jiří, Cvek, Boris, Pavlíček, Marek, Šindelář, Zdeněk, Žák, Zdirad
Předmět:
Zdroj: Journal of Coordination Chemistry; 9/10/2003, Vol. 56 Issue 13, p1123-1129, 7p, 2 Diagrams, 4 Charts
Abstrakt: Ni(II) di(pentyl)dithiocarbamates of composition [Ni(Pe 2 dtc) 2 ], [NiX(Pe 2 dtc)(PPh 3 )] (X = Cl, Br, I, NCS), [Ni(NCS)(Pe 2 dtc)(PBut 3 )], [Ni(Pe 2 dtc)(PPh 3 ) 2 ]ClO 4 and [Ni(Pe 2 dtc)(PPh 3 ) 2 ]PF 6 (Pe 2 dtc = di(pentyl)dithio-carbamate, PPh 3 = triphenylphosphine, PBut 3 = tributylphosphine) have been synthesized. The complexes have been characterized by the usual methods. X-ray structure analyses confirmed the nature of [NiI(Pe 2 dtc)(PPh 3 )] and [Ni(Pe 2 dtc)(PPh 3 ) 2 ]ClO 4 complexes. [ABSTRACT FROM AUTHOR]
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