| Autor: |
Mal DK; Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085, India., Das S; Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085, India.; Homi Bhabha National Institute (HBNI), Mumbai 400094, India., Nigam S; Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085, India.; Homi Bhabha National Institute (HBNI), Mumbai 400094, India., Mandal BP; Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085, India.; Homi Bhabha National Institute (HBNI), Mumbai 400094, India., Kaiwart R; Homi Bhabha National Institute (HBNI), Mumbai 400094, India.; High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Mumbai 400085, India., Poswal HK; Homi Bhabha National Institute (HBNI), Mumbai 400094, India.; High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Mumbai 400085, India., Sudarsan V; Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085, India.; Homi Bhabha National Institute (HBNI), Mumbai 400094, India., Majumder C; Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085, India.; Homi Bhabha National Institute (HBNI), Mumbai 400094, India., Tyagi AK; Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085, India.; Homi Bhabha National Institute (HBNI), Mumbai 400094, India. |
| Abstrakt: |
Even though technological relevance for nuclear and oxide fuel cell application has persuaded a large number of investigations on the Y 2 Zr 2 O 7 system, its local structure still remains ambiguous and debatable. While diffraction-based investigations claim a lack of local ordering, the MAS NMR and Raman spectroscopic investigations speculate the presence of local ordering. Besides, a correlation between the local and global structures of Y 2 Zr 2 O 7 is also missing to date. Present work attempts to get deeper insights into the local structure of Y 2 Zr 2 O 7 and correlate the local structure with global disordering. Complementary investigation using multiple strategies (XRD, RAMAN, electron microscopy, DFT calculations) revealed the presence of pyrochlore-like features in globally disordered Y 2 Zr 2 O 7 . Globally distributed "local probe ions" (Sn 4+ by MAS NMR and Eu 3+ by photoluminescence (PL)) were utilized for establishing the correlation between local and global structures. The 119 Sn MAS NMR spectra possess the shoulder peak bearing chemical shift values, which are improbable under complete cationic randomization. The emission and decay profiles of the Eu 3+ ion recommend positioning of few probe ions at the centrosymmetric site, which was further reinforced by crystal field splitting and lifetime values. Thus, both NMR and PL results reaffirm the existence of a pyrochlore-like atomic arrangement in predominantly defective fluorite Y 2 Zr 2 O 7 phase. These discernible pyrochlore-like features have been envisaged to be emanating from unevenness in bond strength and ionicity/covalency of Y-O and Zr-O bonds. Cationic and anionic randomization energetically endorses global disordering, but the bonding disparity induces short-range ordering. It is believed that the presented findings will guide future research in regulating the physicochemical properties of Y 2 Zr 2 O 7 for the target applications. |
