| Autor: |
Rahane GK; Department of Materials Engineering, Indian Institute of Science, Bangalore 560012, India., Singh B; Department of Materials Engineering, Indian Institute of Science, Bangalore 560012, India., Roy A; Environment and Sustainability Institute, University of Exeter, Penryn Campus, Cornwall TR10 9FE, U.K., Saykar NG; Department of Materials Engineering, Indian Institute of Science, Bangalore 560012, India., Mandal A; Department of Materials Engineering, Indian Institute of Science, Bangalore 560012, India., Afria D; Department of Materials Engineering, Indian Institute of Science, Bangalore 560012, India., Jadhav YA; Symbiosis Center for Nanoscience and Nanotechnology (SCNN), Symbiosis International (Deemed University) (SIU), Lavale, Pune 412115 Maharashtra, India., Mali SS; Polymer Energy Materials Laboratory, School of Chemical Engineering, Chonnam National University, Gwangju 61186, South Korea., Dzade NY; Department of Energy and Mineral Engineering, Pennsylvania State University, University Park, Pennsylvania 16802, United States., Rondiya SR; Department of Materials Engineering, Indian Institute of Science, Bangalore 560012, India. |
| Abstrakt: |
The efficiency of mesoporous perovskite solar cells (mp-PSCs) is significantly influenced by favorable charge transport properties across their various interfaces. The interfaces involving compact-TiO 2 , mesoporous electron transport layer (ETL), and perovskite layer are particularly vital for high-performing devices. Our study presents a combined experimental and computational approach, specifically employing density functional theory, to explore the impact of mesoporous-ETL/perovskite interface properties on carrier transport. These properties are examined in relation to the phases and morphologies of the mesoporous layer. Different phases of TiO 2 , including anatase, rutile, and brookite, and various morphologies such as nanocubes, nanorods, and disks/clusters, were synthesized using a simple hydrothermal synthesis route. They constitute the mesoporous layer, and Cs 0.05 FA 0.84 MA 0.14 PbI 2.55 Br 0.45 is used as the perovskite absorber in mp-PSCs. The performance of the resulting mesoporous-TiO 2 (mp-TiO 2 ) device was investigated in relation to the different phases and morphologies of mp-TiO 2 . The mp-PSCs with the anatase phase as the mesoporous ETL exhibited the highest device parameters, including power conversion efficiency of 19.15%, short-circuit current density of 22.55 mA/cm 2 , fill factor of 76.50%, and open-circuit voltage of 1.11 V. The superior performance of the anatase structure is attributed to its promising band edge alignment, which results from a small negative conduction band offset compared to other phases, thereby enhancing carrier transport. This study underscores the potential of interface optimization to improve device performance. By investigating the device performance across different phases and morphologies of the mp-TiO 2 layer, we can pave the way for the design of next-generation energy devices. |
