Crystal structure and Hirshfeld surface analysis of tri-chlorido-(1,10-phenanthroline-κ 2 N , N ')phenyltin(IV).

Autor: Benlatreche T; Environmental and Structural Molecular Chemistry Research Unit URCHEMS Faculty of Exact Sciences University of Constantine 1-Mentouri Brothers 25000 Algeria.; National Higher School for Hydraulics, Abdellah Arbaoui, Blida, Algeria., Bensegueni MA; Environmental and Structural Molecular Chemistry Research Unit URCHEMS Faculty of Exact Sciences University of Constantine 1-Mentouri Brothers 25000 Algeria., Dénès G; Laboratory of Solid State Chemistry and Mössbauer Spectroscopy, Chemistry and Biochemistry Department, Concordia University, Montreal, Canada., Golhen S; CNRS, Rennes Institute of Chemical Sciences - UMR 6226, University of Rennes, France., Merazig H; Environmental and Structural Molecular Chemistry Research Unit URCHEMS Faculty of Exact Sciences University of Constantine 1-Mentouri Brothers 25000 Algeria.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2024 Sep 24; Vol. 80 (Pt 10), pp. 1039-1043. Date of Electronic Publication: 2024 Sep 24 (Print Publication: 2024).
DOI: 10.1107/S2056989024009150
Abstrakt: The title compound, [Sn(C 6 H 5 )Cl 3 (C 12 H 8 N 2 )], which was obtained by the reaction between 1,10-phenanthroline and phenyl-tin trichloride in methanol, exhibits intra-molecular hydrogen-bonding inter-actions involving the chlorine and hydrogen atoms. Crystal cohesion is ensured by inter-molecular C-H⋯Cl hydrogen bonds, as well as Y - X ⋯π and π-stacking inter-actions involving three different aromatic rings with centroid-centroid distances of 3.6605 (13), 3.9327 (14) and 3.6938 (12) Å]. Hirshfeld surface analysis and the associated two-dimensional fingerprint plots reveal significant contributions from H⋯H (30.7%), Cl⋯H/H⋯Cl (32.4%), and C⋯H/H⋯C (24.0%) contacts to the crystal packing while the C⋯C (6.2%), C⋯Cl/Cl⋯C (4.1%), and N⋯H/H⋯N (1.7%) inter-actions make smaller contributions.
(© Benlatreche et al. 2024.)
Databáze: MEDLINE
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