8-Hy-droxy-quinolinium tri-chlorido-(pyridine-2,6-di-carb-oxy-lic acid-κ 3 O , N , O ')copper(II) dihydrate.

Autor: Nazarov YE; Termez State University, Barkamol Avlod Street 43, Termez City, Uzbekistan., Turaev KK; Termez State University, Barkamol Avlod Street 43, Termez City, Uzbekistan., Suyunov JR; Termez State University, Barkamol Avlod Street 43, Termez City, Uzbekistan., Alimnazarov BK; Termez State University, Barkamol Avlod Street 43, Termez City, Uzbekistan., Rasulov AA; Institute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, 100125, M. Ulugbek Str. 83, Tashkent, 700125, Uzbekistan., Ibragimov BT; Institute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, 100125, M. Ulugbek Str. 83, Tashkent, 700125, Uzbekistan., Ashurov JM; Institute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, 100125, M. Ulugbek Str. 83, Tashkent, 700125, Uzbekistan.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2024 Sep 24; Vol. 80 (Pt 10), pp. 1049-1053. Date of Electronic Publication: 2024 Sep 24 (Print Publication: 2024).
DOI: 10.1107/S2056989024009186
Abstrakt: The title compound, (C 9 H 8 NO)[CuCl 3 (C 7 H 5 NO 4 )]·2H 2 O, was prepared by reacting Cu II acetate dihydrate, solid 8-hy-droxy-quinoline (8-HQ), and solid pyridine-2,6-di-carb-oxy-lic acid (H 2 pydc), in a 1:1:1 molar ratio, in an aqueous solution of dilute hydro-chloric acid. The Cu II atom exhibits a distorted CuO 2 NCl 3 octa-hedral geometry, coordinating two oxygen atoms and one nitro-gen atom from the tridentate H 2 pydc ligand and three chloride atoms; the nitro-gen atom and one chloride atom occupy the axial positions with Cu-N and Cu-Cl bond lengths of 2.011 (2) Å and 2.2067 (9) Å, respectively. In the equatorial plane, the oxygen and chloride atoms are arranged in a cis configuration, with Cu-O bond lengths of 2.366 (2) and 2.424 (2) Å, and Cu-Cl bond lengths of 2.4190 (10) and 2.3688 (11) Å. The asymmetric unit contains 8-HQ + as a counter-ion and two uncoordinated water mol-ecules. The crystal structure features strong O-H⋯O and O-H⋯Cl hydrogen bonds as well as weak inter-actions including C-H⋯O, C-H⋯Cl, Cu-Cl⋯π, and π-π, which result in a three-dimensional network. A Hirshfeld surface analysis indicates that the most important contributions to the crystal packing involving the main residues are from H⋯Cl/Cl⋯H inter-actions, contributing 40.3% for the anion. Weak H⋯H contacts contribute 13.2% for the cation and 28.6% for the anion.
(© Nazarov et al. 2024.)
Databáze: MEDLINE
Externí odkaz: