| Autor: |
Ding XX; Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Institute of Physical Chemistry, College of Chemistry and Materials Science, Zhejiang Normal University, No.688, Yingbin Avenue, Jinhua, Zhejiang, 321004, China. jzg@zjnu.cn., Yang WZ; Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Institute of Physical Chemistry, College of Chemistry and Materials Science, Zhejiang Normal University, No.688, Yingbin Avenue, Jinhua, Zhejiang, 321004, China. jzg@zjnu.cn., Yao SJ; Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Institute of Physical Chemistry, College of Chemistry and Materials Science, Zhejiang Normal University, No.688, Yingbin Avenue, Jinhua, Zhejiang, 321004, China. jzg@zjnu.cn., Tong XY; Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Institute of Physical Chemistry, College of Chemistry and Materials Science, Zhejiang Normal University, No.688, Yingbin Avenue, Jinhua, Zhejiang, 321004, China. jzg@zjnu.cn., Ling YX; Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Institute of Physical Chemistry, College of Chemistry and Materials Science, Zhejiang Normal University, No.688, Yingbin Avenue, Jinhua, Zhejiang, 321004, China. jzg@zjnu.cn., Jiang ZG; Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Institute of Physical Chemistry, College of Chemistry and Materials Science, Zhejiang Normal University, No.688, Yingbin Avenue, Jinhua, Zhejiang, 321004, China. jzg@zjnu.cn., Wang CF; GuangDong Engineering Technology Research Center of Biomaterials, Institute of Biological and Medical Engineering, Guangdong Academy of Sciences, Guangzhou, China. cfwang@yzu.edu.cn., Zhan CH; Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Institute of Physical Chemistry, College of Chemistry and Materials Science, Zhejiang Normal University, No.688, Yingbin Avenue, Jinhua, Zhejiang, 321004, China. jzg@zjnu.cn. |
| Abstrakt: |
This review summarizes the progress in the research on polyoxometalate (POM)-decorated gold (Au) and silver (Ag) core-shell structures (Au/Ag@POMs), emphasizing their substantial application potential in catalysis, medicine, and biology. It outlines the central strategies for fabricating Au/Ag@POMs with diverse morphologies and dimensions, leveraging POMs as protective ligands and reducing agents as well as for ligand exchange. Of particular note is the focus on the analysis of the nanoparticle size, shape, and intricate architecture of POM shells using cryo-electron microscopy techniques. By integrating recent findings on atomically precise POM-stabilized nanoclusters, this review delves deeper into understanding surface interface structures, intrinsic atomic architectures, and electronic interactions between POM shells and metallic cores. Collectively, advancements in this field underscore significant strides in the controllable synthesis and precise structural manipulation of Au/Ag@POM architectures, thus paving the way for engineering high-performance metal catalysts. |
