Supramolecular assembly of phenanthrene-DNA conjugates into light-harvesting nanospheres.

Autor:	Thiede J; Department of Chemistry, Biochemistry, and Pharmaceutical Sciences, University of Bern Freiestrasse 3 CH-3012 Bern Switzerland robert.haener@unibe.ch https://www.haener.dcbp.unibe.ch., Schneeberger T; Department of Chemistry, Biochemistry, and Pharmaceutical Sciences, University of Bern Freiestrasse 3 CH-3012 Bern Switzerland robert.haener@unibe.ch https://www.haener.dcbp.unibe.ch., Iacovache I; Institute of Anatomy, University of Bern Baltzerstrasse 2 CH-3012 Bern Switzerland., Langenegger SM; Department of Chemistry, Biochemistry, and Pharmaceutical Sciences, University of Bern Freiestrasse 3 CH-3012 Bern Switzerland robert.haener@unibe.ch https://www.haener.dcbp.unibe.ch., Zuber B; Institute of Anatomy, University of Bern Baltzerstrasse 2 CH-3012 Bern Switzerland., Häner R; Department of Chemistry, Biochemistry, and Pharmaceutical Sciences, University of Bern Freiestrasse 3 CH-3012 Bern Switzerland robert.haener@unibe.ch https://www.haener.dcbp.unibe.ch.
Jazyk:	angličtina
Zdroj:	New journal of chemistry = Nouveau journal de chimie [New J Chem] 2024 Aug 30; Vol. 48 (36), pp. 15731-15734. Date of Electronic Publication: 2024 Aug 30 (Print Publication: 2024).
DOI:	10.1039/d4nj02411g
Abstrakt:	The self-assembly of highly functionalized phenanthrene-DNA conjugates into supramolecular nanostructures is presented. DNA oligomers modified with phenanthrene residues at the 3'-end and internal positions self-assemble into spherical nanostructures. The nanospheres exhibit light-harvesting properties. Upon irradiation of phenanthrene, the excitation energy is transferred along phenanthrene units, resulting in phenanthrene-pyrene exciplex formation. Competing Interests: There are no conflicts to declare. (This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.)
Databáze:	MEDLINE
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